Chlorine: The Ultimate Guide to Its History, Properties, and Hazards

by Joost Nusselder | Last Updated:  June 2, 2022

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Chlorine is a versatile chemical element found in many compounds. It’s commonly used to make bleach, disinfectants, and other products. With its symbol Cl and atomic number 17, it’s the second-lightest of the halogens and appears between fluorine and bromine in the periodic table.

Chlorine is a yellow-green gas at room temperature, but liquefies near room temperature and at −101 °C, it’s a yellow-green crystalline solid. Its highly reactive nature makes it useful in the production of plastics, pesticides, pharmaceuticals, and solvents. Additionally, it’s a popular choice for sanitizing drinking water and swimming pools.

What is chlorine

Chlorine: More Than Just a Bleach

Chlorine is a highly reactive chemical element that is normally found in a variety of compounds. It is associated with a long list of products and processes that people use every day. From household cleaning to industrial production, chlorine is a common chemical that has a wide range of applications.

Properties of Chlorine

Chlorine is a yellow-green gas at room temperature and is highly irritating to the eyes and respiratory system. It has a strong, pungent odor that can remain in the air for a long time. Chlorine is also highly corrosive and can react with a variety of substances, including hydrogen, sodium, and acids.

Production and Preparation

Chlorine is produced industrially by the electrolysis of sodium chloride (table salt) in a process called chloralkali. It can also be prepared by reacting hydrochloric acid with manganese dioxide. Chlorine can exist as a gas, liquid, or dissolved in water as hypochlorous acid.

Applications of Chlorine

Chlorine has a wide range of applications in various industries, including:

  • Water treatment plants use chlorine to disinfect water and kill harmful bacteria.
  • The paper industry uses chlorine to bleach paper products.
  • The chemical industry uses chlorine to produce a variety of chemicals, including PVC and solvents.
  • Household cleaning products often contain chlorine bleach as a disinfectant.
  • Chlorine is used in the production of many common products, including plastics, textiles, and pharmaceuticals.

Hazards of Chlorine Exposure

Chlorine can be highly toxic and exposure to high levels can cause serious health problems, including respiratory distress and even death. Chlorine gas is explosive when pressurized or cooled and can react with moisture to form corrosive hypochlorous acid. Chlorine exposure can occur through inhalation, ingestion, or skin contact.

The Fascinating History of Chlorine

  • Chlorine was first discovered in 1774 by a Swedish pharmacist named Carl Wilhelm Scheele.
  • He described the greenish-yellow gas after reacting hydrochloric acid with manganese dioxide.
  • Sir Humphry Davy recognized the gas as an element in 1810 and named it based on the Greek word for its color, “khloros.”

Early Uses and Production

  • Chlorine was already in use before it was recognized as an element.
  • The ancient Greeks and Romans used a mixture of chlorine and hydrochloric acid to whiten cloth and disinfect water.
  • In the 18th century, chlorine was prepared by reacting hydrochloric acid with manganese dioxide.
  • Later, it was produced by adding hydrochloric acid to bleaching powder.
  • In the 19th century, the production of chlorine increased significantly, with approximately 35,000 tons produced per year.

Chlorine in Science and Research

  • Chlorine is a highly reactive element and is found in nature as a compound.
  • It is a key element in the preparation of a variety of compounds, including chlorides and chlorates.
  • Chlorine is also used in the manufacture of a number of products, including pesticides, plastics, and pharmaceuticals.
  • Despite its strong and active nature, chlorine is an essential element for life, as it is a key component of chlorophyll, the green pigment found in plants.

Chlorine in Warfare and Arsenal

  • Chlorine was famously used as a chemical weapon during World War I.
  • It was released as a gas and caused severe respiratory damage to soldiers.
  • Chlorine gas was also used in the Second World War as part of the chemical arsenal.
  • Today, chlorine is still used in the manufacture of chemical weapons and is included in the arsenal of many countries.

Chlorine in Water Treatment and Consumption

  • Chlorine is commonly used to disinfect water and kill harmful bacteria and viruses.
  • It is added to water in small parts per million (ppm) and is considered safe for consumption.
  • Despite its use in water treatment, some people are concerned about the possible health effects of consuming chlorine.
  • Chlorine is also used in the production of bottled water and other beverages.

Chlorine in Storage and Delivery

  • Chlorine is a highly reactive and volatile element and must be stored and transported carefully.
  • It is usually stored in steel cylinders equipped with safety devices to prevent leaks and spills.
  • Chlorine is delivered to industrial users by technical delivery companies that are equipped to handle the element safely.
  • Despite the potential hazards of chlorine, it is a common and essential element in many industries and products.

Chlorine: Where Does It Come From?

  • Chlorine is a chemical element that occurs naturally in small amounts in the Earth’s crust.
  • It is found in nature dissolved in salts in seawater and in the deposits of salt mines.
  • Chlorine is also present in certain minerals and in some lakes and dead sea waters.
  • According to analysis, chlorine is the 21st most abundant element in the Earth’s crust.

Electrolysis Process

  • The electrolysis process involves passing an electric current through a liquid or solution to produce chemical reactions.
  • In the case of chlorine production, a solution of brine (dissolved sodium chloride) is used.
  • The solution is placed in an electrolytic cell, which contains a diaphragm or membrane to separate the anode and cathode compartments.
  • When an electric current is passed through the solution, chlorine gas is produced at the anode and hydrogen gas is produced at the cathode.
  • The chlorine gas is then collected and the hydrogen gas is usually vented.
  • The process requires a great deal of energy and produces a large amount of heat.
  • The chlorine gas produced is usually not pure and contains small amounts of other compounds, such as hydrochloric acid and oxygen.
  • These impurities can be removed by switching to a different method of production or by further processing the chlorine gas.

Other Methods of Production

  • Chlorine can also be produced by reacting hydrochloric acid and manganese dioxide or hydrochloric acid and sulfuric acid with certain minerals.
  • These methods are less common and require higher concentrations of chlorine.
  • Chlorine can also occur as a gas in certain natural environments, such as volcanic areas or salt lakes.
  • However, the concentrations of chlorine in these environments are much smaller than those produced through industrial methods.

Reserves and Comparison

  • Chlorine is an abundant element, with reserves estimated to be around 1.5 billion tonnes.
  • In comparison, the reserves of other important elements, such as potassium and sodium, are much greater.
  • Chlorine is highly reactive and is rarely found in its free form in nature.
  • Instead, it is usually found in compounds with other elements, such as sodium chloride (table salt) or hydrochloric acid.

The Many Uses of Chlorine

Chlorine is best known for its ability to disinfect water, making it safe for human consumption. This process involves adding chlorine compounds to water, which react to form hypochlorous acid and hypochlorite ions. These compounds are highly effective at killing bacteria, viruses, and other harmful microorganisms that can cause disease. Chlorine is also used in the treatment of sewage and industrial waste to remove organic matter and prevent putrefaction.

Bleaching and Paper Production

Chlorine is commonly used as a bleaching agent in the production of paper and cloth. The process involves adding chlorine dioxide or chlorinated organic and inorganic compounds to the pulp, which helps to break down lignin and other impurities. This results in a pure, white product that is ideal for a range of applications, from construction to food packaging.

Cooling Towers and Metal Production

Chlorine is also used in cooling towers and metal production. In these applications, chlorine gas is typically used to prevent the growth of bacteria and other microorganisms that can cause corrosion and other damage. Chlorine is also used in the production of vinyl and other chemical compounds, as well as in the manufacture of insulation and other industrial materials.

Medical and Household Cleaning

Chlorine is a common ingredient in many medical and household cleaning products, including bleach. Household bleach is chlorine dissolved in water and is highly effective at killing bacteria and other harmful microorganisms. Chlorine is also used in the production of disinfectants and sterilizing agents used in hospitals and other medical facilities.

Animal Feed and Bio Film Development

Chlorine is also used in the production of animal feed, as well as in the development of bio films and other microbial communities. In these applications, chlorine is used to control the spread of harmful bacteria and other microorganisms, allowing for the growth of beneficial organisms that play an essential role in various biological processes.

Paper and Cleaning Products

Chlorine is also used in the production of paper and cleaning products. In these applications, chlorine is used to bleach and disinfect materials, producing a pure and sterile product that is safe for use in a variety of settings. Many companies use chlorine in their routine manufacturing processes, as it is highly effective and significantly reduces the risk of contamination and other hazards.

Chlorine Hazards: Don’t Get Burned!

  • Exposure to low levels of chlorine can result in nose, throat, and eye irritation.
  • At higher levels, breathing chlorine gas may result in changes in breathing rate and coughing, and damage to the lungs.
  • Inhalation of higher concentrations of chlorine gas (>15 ppm) can rapidly lead to respiratory distress with airway constriction and accumulation of fluid in the lungs (pulmonary edema).
  • Chlorine is highly toxic and can cause potentially serious health effects.
  • Chlorine gas is a strong irritant to the eyes, nose, and throat, and can cause severe eye and respiratory damage.
  • Chlorine gas is also a potent oxidizing agent and can react with a variety of materials to produce highly reactive and potentially explosive mixtures.
  • Chlorine gas is a corrosive substance that can cause severe burns and tissue damage upon contact with the skin or eyes.
  • Chlorine gas can also react with water to produce hydrochloric acid, which is highly corrosive and can cause severe burns and tissue damage upon contact with the skin or eyes.

Fire and Explosion Hazards

  • Chlorine gas is highly reactive and can ignite or explode upon contact with a variety of materials, including aluminum, zinc, diethyl zinc, calcium, and many others.
  • Chlorine gas can also react with hydrogen to produce explosive mixtures.
  • Chlorine gas can initiate the ignition of other flammable or combustible materials, such as fuels, oils, and gases.
  • Chlorine gas can produce fumes that are highly irritating and potentially toxic.
  • Chlorine gas can also react with other oxidizing agents to produce highly reactive and potentially explosive mixtures.
  • Chlorine gas is a highly oxidizing substance that can cause fires and explosions upon contact with many common materials.
  • Chlorine gas can also react with organic materials to produce toxic and potentially explosive mixtures.

Handling and Storage Hazards

  • Chlorine gas is a highly reactive and corrosive substance that requires special handling and storage procedures.
  • Chlorine gas must be stored in a dry, cool, well-ventilated area away from excess heat, sparks, and flames.
  • Chlorine gas must be stored in containers made of steel or other materials that are compatible with chlorine gas.
  • Chlorine gas must be handled with caution and care to avoid exposure to the eyes, skin, and respiratory system.
  • Chlorine gas must be used only in well-ventilated areas with appropriate personal protective equipment and absorbents.
  • Chlorine gas must be transported and handled only by trained and experienced personnel who are familiar with the hazards and risks associated with chlorine gas.
  • Chlorine gas must be stored and handled separately from incompatible materials, such as oxidizing agents, fuels, and organic materials.
  • Chlorine gas must be stored and handled in accordance with all applicable regulations, alerts, and guidelines, including the TSP and MMG medical management guidelines for toxic substances.

Presence and Reactivity Hazards

  • Chlorine gas is a highly reactive substance that can react with a wide variety of materials to produce toxic and potentially explosive mixtures.
  • Chlorine gas is a strong oxidizing agent that can cause changes in the reactivity and properties of other substances.
  • Chlorine gas can react with water to produce hydrochloric acid, which is highly corrosive and can cause severe burns and tissue damage upon contact with the skin or eyes.
  • Chlorine gas can react with other oxidizing agents to produce highly reactive and potentially explosive mixtures.
  • Chlorine gas can react with organic materials to produce toxic and potentially explosive mixtures.
  • Chlorine gas can react with metals, such as aluminum and zinc, to produce highly reactive and potentially explosive mixtures.
  • Chlorine gas can react with hydrogen to produce explosive mixtures.
  • Chlorine gas can react with a variety of other substances to produce highly reactive and potentially explosive mixtures.

Profile and Supports Hazards

  • Chlorine gas is a highly hazardous substance that requires special handling and storage procedures.
  • Chlorine gas is a potent oxidizing agent that can cause changes in the reactivity and properties of other substances.
  • Chlorine gas is a highly reactive substance that can react with a wide variety of materials to produce toxic and potentially explosive mixtures.
  • Chlorine gas is a corrosive substance that can cause severe burns and tissue damage upon contact with the skin or eyes.
  • Chlorine gas is a highly toxic substance that can cause serious health effects upon exposure.
  • Chlorine gas is a highly hazardous substance that requires special training, equipment, and procedures to handle and store safely.
  • Chlorine gas is a highly hazardous substance that is used in numerous fields and applications, including water treatment, energy production, materials synthesis, and many others.
  • Chlorine gas is a highly hazardous substance that is known to be incompatible with a wide variety of other substances, including many common materials.

When Chlorine Strikes: Treating Chlorine Poisoning

Chlorine is a highly reactive chemical that can cause severe harm to the body upon exposure. If you suspect that you or someone you know has been exposed to chlorine, it is important to recognize the symptoms of chlorine poisoning, which include:

  • Burning sensation in the eyes, nose, and throat
  • Coughing and wheezing
  • Chest pain and difficulty breathing
  • Nausea and vomiting
  • Skin irritation and burns
  • Headache and dizziness
  • Rapid heartbeat and low blood pressure

Immediate Actions to Take

If you or someone you know has been exposed to chlorine and is experiencing any of the above symptoms, it is important to take immediate action. Here are some steps you can take:

  • Move the affected person to an area with fresh air immediately.
  • Remove any contaminated clothing and rinse the affected skin with water for at least 15 minutes.
  • If the eyes are affected, rinse them with water for at least 15 minutes, holding the eyelids open.
  • Call 911 or seek medical attention immediately.

Medical Treatment for Chlorine Poisoning

Chlorine poisoning can be a medical emergency, and it is important to seek medical attention as soon as possible. Here are some treatments that may be administered in a hospital:

  • Oxygen therapy to help with breathing difficulties
  • Bronchodilators to open up the airways
  • Intravenous fluids to help with dehydration
  • Steroids to reduce inflammation in the body
  • Antihistamines to reduce allergic reactions
  • Pain medication to alleviate discomfort

Preventing Chlorine Poisoning

The best way to treat chlorine poisoning is to prevent it from happening in the first place. Here are some tips to reduce your risk of exposure:

  • Always handle chlorine with care and wear protective clothing and equipment when working with it.
  • Use chlorine in well-ventilated areas.
  • Never mix chlorine with other chemicals, especially ammonia, as this can create toxic fumes.
  • Store chlorine in a secure location away from children and pets.
  • Follow all safety guidelines and instructions when using chlorine.

Remember, chlorine poisoning can be a severe medical emergency. If you suspect that you or someone you know has been affected by chlorine, seek medical attention immediately.

Conclusion

So, chlorine’s a chemical element that’s used for disinfecting water and producing many products we use every day. It’s also used in warfare, so be careful with it! It’s important to know the dangers of chlorine and the chemicals it reacts with so you can protect yourself. So, don’t be afraid to ask questions and get the right information. You can do it!

Joost Nusselder, the founder of Lakeside Smokers is a content marketer, dad and loves trying out new food with BBQ Smoking (& Japanese food!) at the heart of his passion, and together with his team he's been creating in-depth blog articles since 2016 to help loyal readers with recipes and cooking tips.